I have a Dell 15z 5523.I recently formatted the SSD and HDD. Now I want to boot from the 32GB SSD but keeping the default disk(Storage for Users,Program files etc.) as the HDD. What is the process for doing this?
You'll need a larger mSATA drive - 32G is far too small to load and run Windows from. 128G is a bare minimum - 256 would be better.
Once you've replaced the SSD, you will need to reload the operating system from scratch.