You do NOT want to format the second E:/ hard drive, formatting will erase all the data, including My Documents.
Go to My Computer, right click the E:/ drive, click Open and select Documents and Settings and you should find My Documents files and folders. Open it and right click the file or folder and drag it to the new hard drive's My Documents.
You can only transfer files, all programs and applications must be reinstalled from their disks or from the publisher's website.
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If my answer was helpful, please click: Kudos Forum Member since 2001 I am not employed by Dell