internet seaperating/ specifying

oki. so. i have internet, wireless. and i also have a wireless internet usb. i want my laptop one the normal one, and the usb one to be the internet for a certian program. is there a way to do that? or no?

so say, eg., laptop WiLan card for youtube, and usb for like, skype/ minecraft/ msn

um, yea. if i cant ok. if i can can you tell me how? i have win 7